Calcium-based sorbent desulfurization in pressurized fluidized-bed combustion power plants
The sulfur removal performance of pressurized, fluidized-bed combustion power plants operated in the range of 16 to 20 atmospheres pressure is evaluated. This pressure range has previously received little attention and is of potential commercial interest. Eleven limestones and dolomites were characterized and tested for sulfation activity under a variety of conditions of temperature, pressure, excess air, and particle size to provide the basis for commercial sulfur removal projections. A pressurized thermogravimetric balance was used to obtain kinetic data. Sorbent particle diameter was found to have a significant effect on the sulfation rate, temperature and excess air less so. Great variation between the behavior of the eleven sorbents was apparent. Increased pressure results in a need for increased gas residence time or reduced sorbent particle size in the bed in order to achieve calcium-to-sulfur ratios compared with lower pressure operation.
- Research Organization:
- Westinghouse Electric Corp., Pittsburgh, PA (USA). Research and Development Center
- OSTI ID:
- 6339796
- Report Number(s):
- EPRI-CS-1847
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
42 ENGINEERING
01 COAL, LIGNITE, AND PEAT
COAL
FLUIDIZED-BED COMBUSTION
DOLOMITE
SORPTIVE PROPERTIES
FLUIDIZED-BED COMBUSTORS
DESULFURIZATION
HOT GAS CLEANUP
PERFORMANCE TESTING
FOSSIL-FUEL POWER PLANTS
LIMESTONE
SULFUR
SORPTION
ADSORBENTS
EXPERIMENTAL DATA
GAS TURBINES
PARTICLE SIZE
PERFORMANCE
POLLUTION CONTROL EQUIPMENT
SULFUR DIOXIDE
ALKALINE EARTH METAL COMPOUNDS
CARBON COMPOUNDS
CARBONACEOUS MATERIALS
CARBONATE ROCKS
CARBONATES
CHALCOGENIDES
CHEMICAL REACTIONS
COMBUSTION
COMBUSTORS
DATA
ELEMENTS
ENERGY SOURCES
EQUIPMENT
FOSSIL FUELS
FUELS
INFORMATION
MACHINERY
MAGNESIUM CARBONATES
MAGNESIUM COMPOUNDS
MATERIALS
MINERALS
NONMETALS
NUMERICAL DATA
OXIDATION
OXIDES
OXYGEN COMPOUNDS
POWER PLANTS
PURIFICATION
ROCKS
SEDIMENTARY ROCKS
SIZE
SULFUR COMPOUNDS
SULFUR OXIDES
SURFACE PROPERTIES
TESTING
THERMAL POWER PLANTS
THERMOCHEMICAL PROCESSES
TURBINES
TURBOMACHINERY
200104* - Fossil-Fueled Power Plants- Components
421000 - Engineering- Combustion Systems
014000 - Coal
Lignite
& Peat- Combustion
200202 - Fossil-Fueled Power Plants- Waste Management- Noxious Gas & Particulate Emissions