A reanalysis of the (010), (020), (100), and (001) rotational levels of [sup 32]S[sup 16]O[sub 2]
Journal Article
·
· Journal of Nondestructive Evaluation; (United States)
OSTI ID:6325475
- Univ. Pierre et Marie Curie, Paris (France). Lab. de Physique Moleculaire et Applications
- National Inst. of Standards and Technology, Gaithersburg, MD (United States). Molecular Physics Div.
- Univ. Paris-Sud, Orsay (France). Lab. de Physique Moleculaire et Applications
Using high-resolution infrared spectra, a reanalysis of the [nu][sub 2], 2[nu][sub 2] [minus] [nu][sub 2], [nu][sub 1], and [nu][sub 3] bands of [sup 32]S[sup 16]O[sub 2] has been performed. These infrared data, combined with the available heterodyne and microwave data, were fitted within their respective experimental accuracies. For the (010) levels it was sufficient to use a Watson-type Hamiltonian, whereas it proved necessary to consider explicitly interaction terms for the [(020)(100)(001)] states. More precisely a [Delta]K = 2 quadratic distortion-correction to the Fermi interaction term was used to treat the interactions between (020) and (100) and a [Delta]K = 3 Coriolis-type term to treat the interactions between (100) and (001).
- OSTI ID:
- 6325475
- Journal Information:
- Journal of Nondestructive Evaluation; (United States), Journal Name: Journal of Nondestructive Evaluation; (United States) Vol. 160:1; ISSN 0195-9298; ISSN JNOED5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
54 ENVIRONMENTAL SCIENCES
540120 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
664400* -- Experimentally Derived Information on Atomic & Molecular Properties-- (1992-)
74 ATOMIC AND MOLECULAR PHYSICS
ACCURACY
AIR POLLUTION MONITORING
CHALCOGENIDES
CORIOLIS FORCE
DATA ANALYSIS
EARTH ATMOSPHERE
ENERGY LEVELS
EXCITED STATES
INFRARED SPECTRA
MONITORING
OXIDES
OXYGEN COMPOUNDS
ROTATIONAL STATES
SPECTRA
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES
540120 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (1990-)
664400* -- Experimentally Derived Information on Atomic & Molecular Properties-- (1992-)
74 ATOMIC AND MOLECULAR PHYSICS
ACCURACY
AIR POLLUTION MONITORING
CHALCOGENIDES
CORIOLIS FORCE
DATA ANALYSIS
EARTH ATMOSPHERE
ENERGY LEVELS
EXCITED STATES
INFRARED SPECTRA
MONITORING
OXIDES
OXYGEN COMPOUNDS
ROTATIONAL STATES
SPECTRA
SULFUR COMPOUNDS
SULFUR DIOXIDE
SULFUR OXIDES