Conversion of cellulosic wastes to liquid fuels
A project to convert various cellulosic materials to quality liquid hydrocarbon transportation fuels is described. The major accomplishment was achieving projected liquid hydrocarbon yields of 30 to 40 gals/ton of cellulosic feedstock (dry, ash free) for synthesis gas compositions corresponding to that obtainable for average feedstocks and using relatively inexpensive cobalt/alumina type impregnated catalysts. The utility of using dolomite to adjust the H/sub 2//CO pyrolysis gas ratio was demonstrated. An iron liquefaction catalyst study was completed that confirmed the detriment of olefins in the feedgas for these type of catalysts (as opposed to cobalt based catalysts. Two completely new fluidized bed reactor systems were designed and installed to accommodate the liquefaction catalyst development work. An extensive simulator study on gasification transfer loop systems resulted in recommendations for system improvements. Modifications of the 6'' fluidized bed liquefaction reactor were also started based on simulator work.
- Research Organization:
- Arizona State Univ., Tempe (USA). Coll. of Engineering and Applied Sciences
- DOE Contract Number:
- AC02-76CS40202
- OSTI ID:
- 6322602
- Report Number(s):
- DOE/CS/40202-T6; COO-2982-83; ON: DE83007978
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
09 BIOMASS FUELS
090122 -- Hydrocarbon Fuels-- Preparation from Wastes or Biomass-- (1976-1989)
140504* -- Solar Energy Conversion-- Biomass Production & Conversion-- (-1989)
CARBOHYDRATES
CATALYSTS
CELLULOSE
CHEMICAL REACTORS
FLUIDIZED BED
FUELS
HYDROCARBONS
LIQUEFACTION
LIQUID FUELS
ORGANIC COMPOUNDS
POLYSACCHARIDES
RECOMMENDATIONS
SACCHARIDES
THERMOCHEMICAL PROCESSES
YIELDS
090122 -- Hydrocarbon Fuels-- Preparation from Wastes or Biomass-- (1976-1989)
140504* -- Solar Energy Conversion-- Biomass Production & Conversion-- (-1989)
CARBOHYDRATES
CATALYSTS
CELLULOSE
CHEMICAL REACTORS
FLUIDIZED BED
FUELS
HYDROCARBONS
LIQUEFACTION
LIQUID FUELS
ORGANIC COMPOUNDS
POLYSACCHARIDES
RECOMMENDATIONS
SACCHARIDES
THERMOCHEMICAL PROCESSES
YIELDS