Properties of the tetraethynylborate anion as a ligand in reactions with tetraamine complexes of nickel(II)

Journal Article · Fri May 01 00:00:00 EDT 1987 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6322558

Shevchenko, Yu N; Esaulenko, A N; Porai-Koshits, M A; Svitsyn, R A; Kukina, G A

New tetra- and hexaamine complex compounds of nickel(II) with mono-, bi-, and tetradentate linear or cyclic amines of the aliphatic series containing both outer-sphere tetraethynylborate anions and (B(C identical with CH)/sub 4/)/sup -/ anions which are coordinated to the metal ion have been synthesized. The possibility of the coordination of ligands having strong acceptor properties in the axial positions of square-planar complexes of nickel(II) has been demonstrated. The dative transfer of electron density from a nickel(II) 3d/sub xz, 3d/sub yz/, or 3d/sub z/sup 2// orbital occupied by an electron pair to vacant acceptor orbitals of the axial ligands, for example, the antibonding ..pi.. orbitals of the C identical with C bonds of the tetraethynylborate anion is allowed in this case.

• Research Organization: L.V. Pisarzhevskii Institute of Physical Chemistry, USSR
• OSTI ID: 6322558
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Vol. 12:7; Other Information: Translated from Koordinatsionnaya Khimiya; 12: No.7, 955-963(Jul 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMINES
COMPLEXOMETRY
BORON COMPLEXES
ELECTRONIC STRUCTURE
STRUCTURAL CHEMICAL ANALYSIS
NICKEL COMPLEXES
ABSORPTION SPECTRA
ANIONS
BINDING ENERGY
CATALYSTS
CATALYTIC EFFECTS
COORDINATION VALENCES
ELECTRIC CONDUCTIVITY
ELECTRON DENSITY
ELECTRON TRANSFER
ELECTRONS
INFRARED SPECTRA
LATTICE VIBRATIONS
LIGANDS
SPIN
SYNTHESIS
ANGULAR MOMENTUM
CHARGED PARTICLES
COMPLEXES
ELECTRICAL PROPERTIES
ELEMENTARY PARTICLES
ENERGY
FERMIONS
IONS
LEPTONS
ORGANIC COMPOUNDS
PARTICLE PROPERTIES
PHYSICAL PROPERTIES
SPECTRA
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* - Chemical & Physicochemical Properties