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Geochemistry of the Cambrian-Ordovician aquifer system in the northern Midwest, United States

Journal Article · · United States Geological Survey, Professional Paper; (USA)
OSTI ID:6316889
Distributions of solutes in aquifers of Cambrian and Ordovician age were studied in Minnesota, Wisconsin, Iowa, Illinois, northwestern Indiana, and northern Missouri to determine the sources of solutes and the probable chemical mechanisms that control regional variations in water quality. The data base used included more than 3,000 ground-water-quality analyses from all major aquifers, but especially from the St. Peter, Jordan, and Mount Simon Sandstones and their equivalents. Regional variations in the water chemistry of glacial drift and other sedimentary units that overlie the Cambrian-Ordovician aquifer system in recharge areas in Minnesota, Iowa, Wisconsin, and Illinois were also studied, but to a lesser degree. The most important chemical variation in the aquifer is the change in water type from calcium-sodium-sulfate-bicarbonate water to sodium-calcium-sulfate-bicarbonate and sodium-chloride waters along the longest regional flow path from northwestern Iowa to the Illinois basin. The most striking aspect of the distribution of dissolved solids and carbon isotopic content of bicarbonate is the increase in concentration and isotopic enrichment from southwestern Wisconsin, southern Minnesota, and northwestern Illinois south toward Missouri. This study indicates that the ground water in the region is thousands of years old. The study also indicates that the major chemical trends in the aquifers probably are related as much to paleohydrogeologic flow systems during Pleistocene time as to the present flow system, which may postdate the retreat of the last ice sheet about 12,000 years ago.
OSTI ID:
6316889
Journal Information:
United States Geological Survey, Professional Paper; (USA), Journal Name: United States Geological Survey, Professional Paper; (USA) Vol. 1405-D; ISSN XGPPA
Country of Publication:
United States
Language:
English