Kinetics of heterogeneously catalyzed tert-amyl methyl ether reactions in the liquid phase
- Helsinki Univ. of Technology, Espoo (Finland). Lab. of Industrial Chemistry
The kinetics of tert-amyl methyl ether (TAME, 2-methoxy-2-methylbutane) reactions was investigated using a commercial ion exchange resin (Amberlyst 16) as catalyst at temperatures between 324 and 354 K. The rates of reaction were determined experimentally in the liquid phase in a continuous stirred tank reactor at a pressure of 0.8 MPa. Kinetic equations derived for three different mechanisms were compared. In the forward reaction the adsorbed methanol reacted with isoamylene (2-methyl-l-butene or 2-methyl-2-butene) striking from the bulk liquid phase, and in the splitting reaction the adsorbed ether split to alcohol and isoamylene. The kinetic equations were written in terms of activities, and the activity coefficients were calculated by the UNIQUAC method. The activation energy was determined to be 95 kJ/mol for the splitting reaction of TAME to 2-methyl-l-butene and methanol and 100 kJ/mol for the splitting reaction of TAME to 2-methyl-2-butene and methanol.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 63152
- Journal Information:
- Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 4 Vol. 34; ISSN IECRED; ISSN 0888-5885
- Country of Publication:
- United States
- Language:
- English
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