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Decomposition Studies of Tetraphenylborate Slurries

Technical Report ·
DOI:https://doi.org/10.2172/630850· OSTI ID:630850
 [1]
  1. Westinghouse Savannah River Company, AIKEN, SC (United States)

This report details the decomposition of aqueous (K,Na) slurries in concentrated salt solutions using a more complete candidate catalyst recipe, extended testing temperatures (40-70 degrees C) and test durations of approximately 1500 hours (9 weeks). This study uses recently developed High-Pressure Liquid Chromatography (HPLC) methods for analysis of tetraphenylborate (TPB-), triphenylborane (3PB) and diphenylborinic acid (2PB). All of the present tests involve non-radioactive simulants and do not include investigations of radiolysis effects.

Research Organization:
Westinghouse Savannah River Co., Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-96SR18500
OSTI ID:
630850
Report Number(s):
WSRC-TR--97-0046; ON: DE98052356
Country of Publication:
United States
Language:
English

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