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Roles of additives and surface control in slurry atomization

Technical Report ·
DOI:https://doi.org/10.2172/6306931· OSTI ID:6306931
This report focuses on the effects of interparticle forces on the rheology and airblast atomization of micronized coal water slurry (CWS). We found that the CWS flow behavior index is determined by the relative importance of the interparticle van der Waals attraction and the interparticle electrostatic repulsion. The former intensifies as the Hamaker constant increases and the interparticle distance reduces while the latter increases as the particle surface charge density increases. The interparticle attraction causes particle aggregation, which breaks down at high shear rates, and thus leads to slurry pseudoplastic behavior. In contrast, the interparticle repulsion prevents particle aggregation and thus leads to Newtonian behavior. Both atomized at low atomizing air pressures (less than 270 kPa) using twin-fluid jet atomizers of various distributor designs. We found that the atomized drop sizes of micronized coal water slurries substantially decrease as the atomizing air pressure exceeds a threshold value. The effects of coal volume fraction, coal particle surface charge, liquid composition and liquid viscosity on slurry atomization can be accounted for by their effects on slurry rheology. 26 refs.
Research Organization:
California State Univ., Long Beach, CA (USA). Dept. of Chemical Engineering
Sponsoring Organization:
DOE/FE
DOE Contract Number:
FG22-88PC88912
OSTI ID:
6306931
Report Number(s):
DOE/PC/88912-T7; ON: DE91005461
Country of Publication:
United States
Language:
English