NMR spectral study of the structure of 2-amino-4-thiazolinones

Journal Article · Wed Oct 01 04:00:00 EDT 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00542789· OSTI ID:6291053

Ramsh, S M; Smorygo, N A; Khrabrova, E S; Ginak, A I

As a consequence of partial double bond nature of the exocyclic C-N bond, 2-methyl-amino-4-thiazolinone exists in DMSO-D/sub 6/ as a mixture of E and Z conformers of the amino form with predominance of the sterically favored E conformer. 2-Phenylimino-4-thiazolidinone in the same solvent exists as a mixture of the E and Z isomers of the imino form.

• Research Organization: Lensovet Leningrad Technological Institute, USSR
• OSTI ID: 6291053
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 22:4; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AMINES
AZOLES
BARYONS
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DMSO
ELECTRONIC STRUCTURE
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
HALOGENATED ALIPHATIC HYDROCARBONS
HEAVY WATER
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROGEN TRANSFER
HYPERFINE STRUCTURE
IMINES
INTERMEDIATE COUPLING
ISOMERS
ISOTOPES
ISOTOPIC EXCHANGE
J-J COUPLING
KETONES
LIGHT NUCLEI
MOLECULAR STRUCTURE
MULTIPLETS
NMR SPECTRA
NUCLEI
NUCLEONS
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
PROTONS
SOLVATION
SOLVENTS
SPECTRA
STABLE ISOTOPES
SULFOXIDES
TEMPERATURE DEPENDENCE
THIAZOLES
WATER