Synthesis, structure, and properties of Ca sub 2 ZnN sub 2
Journal Article
·
· Journal of Solid State Chemistry; (USA)
- Cornell Univ., Ithaca, NY (USA)
The authors report the synthesis and physical properties of the new ternary nitride Ca{sub 2}ZnN{sub 2}, prepared by the reaction of Ca{sub 3}N{sub 2} and Zn in N{sub 2} gas at 680{degree}C. The structure, determined by x-ray powder diffraction and refined by Rietveld profile analysis, is tetragonal (I4/mmm) with a = 3.5835(4) {angstrom}, c = 12.6583(7) {angstrom}, and Z = 2. The structure features condensed nitrogen-centered metal octahedra and a linear coordination of Zn by two nitrogen atoms. Conductivity and magnetic measurements show that Ca{sub 2}ZnN{sub 2} is insulating and diamagnetic.
- OSTI ID:
- 6290992
- Journal Information:
- Journal of Solid State Chemistry; (USA), Journal Name: Journal of Solid State Chemistry; (USA) Vol. 88:2; ISSN 0022-4596; ISSN JSSCB
- Country of Publication:
- United States
- Language:
- English
Similar Records
The synthesis and structure of Sr sub 2 FeO sub 4
Synthesis and structure of two new layered ternary nitrides, SrZrN{sub 2} and SrHfN{sub 2}
Structure of lithium nitride and transition-metal-doped derivatives, Li{sub 3-x-y}Mn{sub x}N (M = Ni, Cu) : a powder neutron diffraction study.
Journal Article
·
Wed May 01 00:00:00 EDT 1991
· Journal of Solid State Chemistry; (United States)
·
OSTI ID:7200990
Synthesis and structure of two new layered ternary nitrides, SrZrN{sub 2} and SrHfN{sub 2}
Journal Article
·
Tue Dec 17 23:00:00 EST 1996
· Inorganic Chemistry
·
OSTI ID:513363
Structure of lithium nitride and transition-metal-doped derivatives, Li{sub 3-x-y}Mn{sub x}N (M = Ni, Cu) : a powder neutron diffraction study.
Journal Article
·
Mon Dec 31 23:00:00 EST 2001
· Chem. Mater.
·
OSTI ID:961118
Related Subjects
36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
360202 -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
360204 -- Ceramics
Cermets
& Refractories-- Physical Properties
ALKALINE EARTH METAL COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM NITRIDES
CHEMICAL PREPARATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
HIGH TEMPERATURE
INFORMATION
MEASURING METHODS
NITRIDES
NITROGEN COMPOUNDS
NUMERICAL DATA
PHYSICAL PROPERTIES
PNICTIDES
SYNTHESIS
TETRAGONAL LATTICES
ZINC COMPOUNDS
ZINC NITRIDES
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
360202 -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
360204 -- Ceramics
Cermets
& Refractories-- Physical Properties
ALKALINE EARTH METAL COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM NITRIDES
CHEMICAL PREPARATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
HIGH TEMPERATURE
INFORMATION
MEASURING METHODS
NITRIDES
NITROGEN COMPOUNDS
NUMERICAL DATA
PHYSICAL PROPERTIES
PNICTIDES
SYNTHESIS
TETRAGONAL LATTICES
ZINC COMPOUNDS
ZINC NITRIDES