Hydrogenation of furfural on polymer-containing catalysts

Journal Article · Mon Sep 01 04:00:00 EDT 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00514986· OSTI ID:6290963

Karakhanov, E A; Neimerovets, E B; Pshezhetskii, V S; Dedov, A G

The catalytic hydrogenation of furfural with molecular hydrogen has been investigated under mild conditions in the presence of metal complex catalysts with a polymeric macroligand. It has been shown that the reaction proceeds according to a consecutive scheme with the formation of furfuryl and tetrahydrofurfuryl alcohols. The kinetics of furfural hydrogenation has been investigated and the order of the reaction established; the rate constants of the first and second stages have been determined. The influence of the solvent and of the metal-to-polymer ratio on the furfural conversion have been investigated.

• Research Organization: M.V. Lomonosov Moscow State Univ., USSR
• OSTI ID: 6290963
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 22:3; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACRYLIC ACID
ALCOHOLS
ALDEHYDES
ALKALI METAL COMPOUNDS
BOROHYDRIDES
BORON COMPOUNDS
CARBOXYLIC ACIDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPARATIVE EVALUATIONS
COMPLEXES
COPOLYMERS
DICARBOXYLIC ACIDS
EFFICIENCY
ESTERS
FURANS
FURFURAL
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
HYDROGENATION
HYDROXY COMPOUNDS
KINETICS
LIGANDS
MALEIC ACID
MATERIALS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SOLVENTS
PALLADIUM COMPLEXES
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
PLATINUM COMPLEXES
PMMA
POLYACRYLATES
POLYMERS
POLYOLEFINS
POLYSTYRENE
POLYVINYLS
QUANTITY RATIO
REACTION KINETICS
RHODIUM COMPLEXES
SEPARATION PROCESSES
SODIUM COMPOUNDS
SOLVENTS
SYNTHETIC MATERIALS
TRANSITION ELEMENT COMPLEXES
YIELDS