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Reactions of aziridine-2-carboxylic acid derivatives with aldehydes and ketones

Journal Article · · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00515064· OSTI ID:6290406
; ; ; ; ;
The reaction of methyl aziridine-2-carboxylate with hydrazine or alkylhydrazines gives the respective hydrazides, which with ketones form 2,2-disubstituted 1,3,4-triazabicyclo-(4.1.0)heptan-5-ones. With aldehydes they form the respective hydrazones. The reaction of the amide and methyl ester of aziridine-2-carboxylic acid with aldehydes gives a series of aziridinocarbinols.
Research Organization:
Institute of Organic Synthesis, Riga, USSR
OSTI ID:
6290406
Journal Information:
Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:6; ISSN CHCCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACID HYDROLYSIS
ALCOHOLS
ALDEHYDES
AMIDES
CARBON 13
CARBON ISOTOPES
CARBOXYLIC ACID ESTERS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
DECOMPOSITION
DEUTERATION
DEUTERIUM COMPOUNDS
DMSO
ESTERS
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HEAVY WATER
HYDRAZIDES
HYDRAZINE
HYDRAZONES
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROGEN TRANSFER
HYDROLYSIS
HYDROXY COMPOUNDS
ISOTOPES
ISOTOPIC EXCHANGE
KETONES
KINETICS
LIGHT NUCLEI
LYSIS
METHANOL
MOLECULAR STRUCTURE
NITROGEN 15
NITROGEN COMPOUNDS
NITROGEN ISOTOPES
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
SOLVOLYSIS
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SULFOXIDES
SYNTHESIS
WATER
YIELDS