Iodocyclization of 2-allylcyclohexanols

Journal Article · Thu Aug 01 04:00:00 UTC 1985 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00504193· OSTI ID:6290224

Gevaza, Yu I; Kupchik, I P; Staninets, V I; Kalinin, V N; Bratolyubova, A G

Iodination of 2-allylcyclohexanol and its 1-methyl and 1-phenyl derivatives gives the corresponding 2-(iodomethyl)octahydrobenzofurans. These are reduced by LiAlH/sub 4/ to the stereoisomeric (2-methyloctahydrobenzofurans. The rate of iodination of 2-allylcyclohexanols is largely independent of their configuration.

• Research Organization: Institute of Organic Chemistry, Kiev, USSR
• OSTI ID: 6290224
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:2; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
ALUMINIUM HYDRIDES
BENZOFURANS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
CYCLOHEXANOL
DEHYDROCYCLIZATION
ENERGY
FURANS
HALOGENATION
HETEROCYCLIC COMPOUNDS
HEXANOLS
HYDRIDES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
IODINATION
ISOMERS
KINETICS
LITHIUM COMPOUNDS
LITHIUM HYDRIDES
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
REDUCTION
SEPARATION PROCESSES
SPECTRA
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
YIELDS