Dehydration of cyclohexanol on aluminum-chromium and aluminum-molybdenum catalysts

Journal Article · Tue Sep 20 00:00:00 EDT 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6289933

Sibarov, D A; Dokuchaeva, T G; Lezdin, S U; Titova, A V; Karpenko, E V

The purpose of this work was to investigate the activity of chromium and molybdenum oxides deposited on ..gamma..-Al/sub 2/O/sub 3/ in the conversion reaction of cyclohexanol. The authors established that chromium oxide deposited on aluminum oxide has a high activity in the dehydration reaction of cyclohexanol. The yield of ketone reached 95 mole %. They showed that Al-Mo catalysts possess emphasized acidic properties, and that the main reaction products with these catalysts are cyclohexene and cyclohexane.

• OSTI ID: 6289933
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Vol. 61:4; Other Information: Translated from Zh. Prikl. Khim.; 61: No. 4, 811-815(Apr 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM OXIDES
CATALYTIC EFFECTS
CHROMIUM OXIDES
CYCLOHEXANOL
DEHYDRATION
MOLYBDENUM OXIDES
CATALYST SUPPORTS
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
CYCLOALKENES
CYCLOHEXANE
CYCLOHEXANONE
HETEROGENEOUS CATALYSIS
IMPREGNATION
KETONES
MATERIALS TESTING
PHENOLS
ALCOHOLS
ALKANES
ALKENES
ALUMINIUM COMPOUNDS
AROMATICS
CATALYSIS
CHALCOGENIDES
CHROMIUM COMPOUNDS
CYCLOALKANES
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SEPARATION PROCESSES
TESTING
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties