Thermochemistry of solutions of potassium alkyl xanthogenates and rubeanic acid with nitrobenzene and other nitrogen-containing compounds

Journal Article · Wed Jul 20 00:00:00 EDT 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6288260

Gorbatov, V V; Bordzilovskii, V Ya; Gerega, V F; Borovoi, A A; Dergunov, Yu I

The ability of rubeanic acid and potassium alkyl xanthogenates to form complexes with one another and also with nitrobenzene and other nitrogen-containing compounds was shown calorimetrically. The composition of these complexes was determined, and the stability constants and enthalpies of formation of the complexes were calculated. It was found that the formation of the potassium alkyl xanthogenate-nitrogen-containing compound complex is dependent on the natures of both the xanthogenate and the nitrogen-containing additive; the strength of the complex increases regularly with increase in the basicity of the nitrogen-containing compound.

• OSTI ID: 6288260
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 61:2; ISSN JAPUA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
ACTIVATION ENERGY
ALCOHOLS
ALKALI METAL COMPOUNDS
AMIDES
AROMATICS
BUTANOLS
CALORIMETRY
CARBONYLATION
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
COMPLEXOMETRY
DECOMPOSITION
ENERGY
ENTHALPY
FORMATION HEAT
HYDROXY COMPOUNDS
MIXING HEAT
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHYSICAL PROPERTIES
POTASSIUM COMPOUNDS
PYROLYSIS
REACTION HEAT
STABILITY
THERMOCHEMICAL PROCESSES
THERMODYNAMIC PROPERTIES