Characterization of hydrolytically solubilized coal
Treating a bituminous coal with potassium hydroxide in glycols at 250/sup 0/C yields a largely soluble product that results from the reduction of polycyclic aromatics and the cleavage of aryl ether linkages. The reduction in aromaticity was demonstrated in two ways. First, the fraction of aromatic carbons (f/sub a/) of the soluble product, which was determined by /sup 13/C NMR, was compared with the f/sub a/ of the whole coal determined by fluorination. Secondly, the aromatic acids produced in a selective oxidation of both the product and coal were compared, and evidence for ether cleavage was obtained from the oxidation results. The effects of rank and different protic solvents on the reaction were examined. 6 figures, 6 tables.
- Research Organization:
- Argonne National Lab., IL
- OSTI ID:
- 6287748
- Journal Information:
- Adv. Chem. Ser.; (United States), Vol. 192
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
BITUMINOUS COAL
HYDROLYSIS
COAL LIQUIDS
CHEMICAL ANALYSIS
AROMATICS
CARBON 13
FLUORINATION
NUCLEAR MAGNETIC RESONANCE
OXIDATION
POLYCYCLIC AROMATIC HYDROCARBONS
SOLUBILITY
BLACK COAL
CARBON ISOTOPES
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
COAL
DECOMPOSITION
ENERGY SOURCES
EVEN-ODD NUCLEI
FLUIDS
FOSSIL FUELS
FUELS
HALOGENATION
HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
LIQUIDS
LYSIS
MAGNETIC RESONANCE
MATERIALS
NUCLEI
ORGANIC COMPOUNDS
RESONANCE
SOLVOLYSIS
STABLE ISOTOPES
010600* - Coal
Lignite
& Peat- Properties & Composition