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Carbon-14 measurements and characterization of dissolved organic carbon in ground water

Thesis/Dissertation ·
OSTI ID:6282407
Carbon-14 was measured in the dissolved organic carbon (DOC) in ground water and compared with /sup 14/C analyses of dissolved inorganic carbon (DIC). Two field sites were used for this study; the Stripa mine in central Sweden, and the Milk River Aquifer in southern Alberta, Canada. The Stripa mine consists of a Precambrian granite dominated by fracture flow, while the Milk River Aquifer is a Cretaceous sandstone aquifer characterized by porous flow. At both field sites, /sup 14/C analyses of the DOC provide additional information on the ground-water age. Carbon-14 was measured on both the hydrophobic and hydrophilic organic fractions of the DOC. The organic compounds in the hydrophobic and hydrophilic fractions were also characterized. The DOC may originate from kerogen in the aquifer matrix, from soil organic matter in the recharge zone, of from a combination of these two sources. Carbon-14 analyses, along with characterization of the organics, were used to determine this origin. Carbon-14 analyses of the hydrophobic fraction in the Milk River Aquifer suggest a soil origin, while /sup 14/C analyses of the hydrophilic fraction suggest an origin within the Cretaceous sediments (kerogen) or from the shale in contact with the aquifer.
Research Organization:
Arizona Univ., Tucson (USA)
OSTI ID:
6282407
Country of Publication:
United States
Language:
English