Dielectric constant of polarizable, nonpolar fluids and suspensions

Journal Article · Sat Oct 01 04:00:00 EDT 1988 · J. Stat. Phys.; (United States)

DOI:https://doi.org/10.1007/BF01011569· OSTI ID:6280387

Cichocki, B; Felderhof, B U

We study the dielectric constant of a polarizable, nonpolar fluid or suspension of spherical particles by use of a renormalized cluster expansion.The particles may have induced multipole moments of any order. We show that the Clausius-Mossotti formula results from a virtual overlap contribution. The corrections to the Clausius-Mossotti formula are expressed with the aid of a cluster expansion. The integrands of the cluster integrals are expressed in terms of two-body nodal connectors which incorporate all reflections between a pair of particles. We study the two- and three-body cluster integrals in some detail and show how these are related to the dielectric virial expansion and to the first term of the Kirkwood-Yvon expansion.

• Research Organization: Institut fuer Theoretische Physik (West Germany)
• OSTI ID: 6280387
• Journal Information: J. Stat. Phys.; (United States), Journal Name: J. Stat. Phys.; (United States) Vol. 53:1-2; ISSN JSTPB
• Country of Publication: United States
• Language: English

Related Subjects

656002* -- Condensed Matter Physics-- General Techniques in Condensed Matter-- (1987-)
657002 -- Theoretical & Mathematical Physics-- Classical & Quantum Mechanics
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
DIELECTRIC MATERIALS
DIELECTRIC PROPERTIES
DIPOLES
DISPERSIONS
ELECTRICAL PROPERTIES
FLUIDS
FUNCTIONS
GREEN FUNCTION
INTEGRALS
LIQUIDS
MANY-BODY PROBLEM
MATERIALS
MATHEMATICAL MODELS
MECHANICS
MULTIPOLES
PARTICLE MODELS
PHYSICAL PROPERTIES
POLARIZATION
RENORMALIZATION
SCATTERING
SERIES EXPANSION
STATISTICAL MECHANICS
SUSPENSIONS
THERMODYNAMICS
THREE-BODY PROBLEM
TWO-BODY PROBLEM
VIRIAL THEOREM