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Title: Method for separating actinides. [Patent application; stripping of Np from organic extractant]

Patent ·
OSTI ID:6270573

An organic solution used for processing spent nuclear reactor fuels is contacted with an aqueous nitric acid solution to strip Np(VI), U(VI), and Pu(IV) from the organic solution into the acid solution. The acid solution is exposed to ultraviolet light, which reduces Np(VI) to Np(V) without reducing U(VI) and Pu(IV). Since the solubility of Np(V) in the organic solution is much lower than that of Np(VI), U(VI), and Pu(IV), a major part of the Np is stripped from the organic solution while leaving most of the U and Pu therein.

DOE Contract Number:
W-7405-ENG-26
Assignee:
Dept. of Energy
OSTI ID:
6270573
Country of Publication:
United States
Language:
English