Oxidation of methyl-substituted anilines in HSO/sub 3/F

Journal Article · Tue Oct 01 00:00:00 EDT 1985 · Dokl. Chem. (Engl. Transl.); (United States)

OSTI ID:6264926

Rudenko, A P; Aver'yanov, S F; Zarubin, M Y

Oxidation reactions of aromatic amines involving electron transfers have been studied in various media. Methyl substituted anilines are oxidized in HSO/sub 3/F in the protonated form, in the aniline cation configuration. Theoretically, their oxidation should lead in the first step to the cation-radical of the aniline cation configuration. The authors study here the electron structure of these particles by the EPR method, their reaction capabilities, and preparative possibilities for utilizing aniline cation oxidation reactions in HSO/sub 3/F. Simultaneously, the structures of cation radicals formed from N-acetyl derivatives of several substituted anilines by the EPR method are studied.

• Research Organization: S.M. Kirov Leningrad Wood Technology Institute
• OSTI ID: 6264926
• Journal Information: Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 281:4; ISSN DKCHA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400* -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
AMINES
AMMONIA
ANILINE
AROMATICS
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
ELECTRON SPIN RESONANCE
ELECTRON TRANSFER
HYDRIDES
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
INORGANIC ACIDS
IONS
KINETICS
MAGNETIC RESONANCE
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
ORGANIC COMPOUNDS
OXIDATION
REACTION KINETICS
RESONANCE
SULFIDES
SULFUR COMPOUNDS
SULFURIC ACID