Carbon dioxide activation: thermodynamics of CO/sub 2/ binding and the involvement of two cobalt centers in the reduction of CO/sub 2/ by a cobalt(I) macrocycle

Journal Article · Wed Jul 06 00:00:00 EDT 1988 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00222a079· OSTI ID:6262767

Fujita, E; Szalda, D J; Creutz, C; Sutin, N

The interaction of CO/sub 2/ with the cobalt (I) macrocycle, CoL/sup +/ L = (14)diene = 5,7,7,12,14,14-hexamethyl-1,4,8,11-reversible binding of CO/sub 2/ to CoL/sup +/ in CH/sub 3/CN as characterized by uv-visible spectroscopy, a CO/sub 2/ reduction in the solid state, of a binuclear species containing the Co-C(OH)-O-Co moiety are described in this article. 22 references, 2 figures.

• Research Organization: Brookhaven National Lab., Upton, NY (USA)
• DOE Contract Number: AC02-76CH00016
• OSTI ID: 6262767
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 110:14; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
COBALT COMPLEXES
COMPLEXES
DIENES
HYDROCARBONS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POLYENES
TRANSITION ELEMENT COMPLEXES