Vapor-liquid equilibrium in binary and ternary mixtures of nitrogen, argon, and methane

Journal Article · Thu Jul 01 04:00:00 EDT 1993 · Journal of Chemical and Engineering Data; (United States)

OSTI ID:6259549

Jin, Zhangli; Liu, Kunyuan; Sheng, Wangwang ^[1]

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1. Beijing Inst. of Chemical Technology (China). Dept. of Chemical Engineering

Vapor-liquid equilibrium (VLE) values are required in technological applications and are fundamental to separation operations. In this work the authors report VLE data on the three binary mixtures and the ternary system of nitrogen, argon, and methane at 122.89 K. The experimental VLE values on the binary mixtures were correlated with the Peng-Robinson equation of state, and used to predict the VLE values for the binary system. The predicted values were than compared with the experimental results. Calculated pressure and vapor composition from the equation are compared with the ternary mixture data. The experimental results are successfully correlated with the Peng-Robinson equation of state.

• OSTI ID: 6259549
• Journal Information: Journal of Chemical and Engineering Data; (United States), Journal Name: Journal of Chemical and Engineering Data; (United States) Vol. 38:3; ISSN JCEAAX; ISSN 0021-9568
• Country of Publication: United States
• Language: English

Related Subjects

03 NATURAL GAS
033000 -- Natural Gas-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ARGON
DATA
DISPERSIONS
ELEMENTS
EQUATIONS
EQUATIONS OF STATE
EQUILIBRIUM
EXPERIMENTAL DATA
FLUIDS
GASES
HYDROCARBONS
INFORMATION
LIQUIDS
METHANE
MIXTURES
NITROGEN
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
RARE GASES
SEPARATION PROCESSES
THERMODYNAMIC PROPERTIES
VAPORS