Neutral metal formyl complexes: generation, reactivity, and models for Fischer--Tropsch catalyst intermediates

Journal Article · Tue Mar 13 23:00:00 EST 1979 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00500a037· OSTI ID:6257396

Tam, W; Wong, W K; Gladysz, J A

Several metal formyl complexes were prepared by reacting Li(C/sub 2/H/sub 5/)/sub 3/BH with metal carbonyl cations containing manganese, rhenium, iridium, and molybdenum. Preparative conditions, percentage yields, thermal stabilities, and /sup 1/H NMR chemical shifts relative to (CH/sub 4/)/sub 4/Si are given for several of the products. Over the course of ten minutes the reaction of HMn(CO)/sub 5/ and HMo(C/sub 5/H/sub 5/)(CO)/sub 3/ resulted in the formation of Mn(CO)/sub 10/ and benzaldehyde. The compounds are used to illustrate the types of intermediates which may be initially formed in Fischer--Tropsch type synthesis. 1 table, 1 scheme.

• Research Organization: Univ. of California, Los Angeles
• OSTI ID: 6257396
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 101:6; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

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10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACYL RADICALS
CARBONYLS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
COMPLEXES
DATA
DATA FORMS
EXPERIMENTAL DATA
FISCHER-TROPSCH SYNTHESIS
FORMYL RADICALS
FURANS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
IRIDIUM COMPLEXES
IRIDIUM COMPOUNDS
ISOLATED VALUES
LITHIUM COMPLEXES
LOW TEMPERATURE
MAGNETIC RESONANCE
MANGANESE COMPLEXES
MANGANESE COMPOUNDS
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SOLVENTS
RADICALS
REACTION INTERMEDIATES
REACTIVITY
RESONANCE
RHENIUM COMPLEXES
RHENIUM COMPOUNDS
SILANES
SILICON COMPOUNDS
SOLVENTS
SPECTRAL SHIFT
STABILITY
SYNTHESIS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS