Hydrogenation of anthraquinone on metal-containing catalysts

Journal Article · Wed Dec 01 00:00:00 EST 1982 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:6255886

Lunin, V V; Markaryan, G L; Chetina, O V

The present work studied the reaction of hydrogen activated on metal-containing catalysts (platinum black, Pt/Al/sub 2/O/sub 3/ (AP-15), and the hydride ZrNiH/sub 2.8/ with anthraquinone. The hydrogenation of anthraquinone bound into a strong donor-acceptor complex on the surface of Al/sub 2/O/sub 3/ and AP-15 and physically absorbed on silica gel was investigated. Results indicated that under conditions of mechanical mixing of silica gel with catalysts containing platinum or hydrides of intermetallic compounds in an atmosphere of hydrogen, anthraquinone physically adsorbed on silica gel is able to undergo hydrogenation at temperature above 100/sup 0/ C with formation of anthracene.

• Research Organization: Lomonosov Moscow State Univ., Moscow (Russian Federation)
• OSTI ID: 6255886
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 264:4-6; Other Information: Translated from Dokl. Akad. Nauk SSSR; 264: No. 4, 884-887(Jun 1982)
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
ANTHRAQUINONES
HYDROGENATION
NICKEL
CATALYTIC EFFECTS
PLATINUM
ALUMINIUM OXIDES
SPECTRA
ALUMINIUM COMPOUNDS
AROMATICS
CHALCOGENIDES
CHEMICAL REACTIONS
ELEMENTS
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
QUINONES
TRANSITION ELEMENTS
010403* - Coal & Coal Products- Hydrogenation- (-1987)