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ZrO sub 2 and ZrO sub 2 /SiC particle reinforced-MoSi sub 2 matrix composites

Conference ·
OSTI ID:6253688
; ; ;  [1];  [2];  [3]
  1. Los Alamos National Lab., NM (United States)
  2. Arizona Materials Lab., Tucson, AZ (United States)
  3. Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Materials Science and Engineering

ZrO{sub 2}-MoSi{sub 2} and ZrO{sub 2}/SiC-MoSi{sub 2} composites were fabricated by hot pressing and hot pressing/HIP at 1700{degrees}C. No reactions between ZrO{sub 2}, SiC, and MoSi{sub 2} were observed. An amorphous silica glassy phase was present in all composites. Composites with unstabilized ZrO{sub 2} particles exhibited the highest room temperature fracture toughness, reaching a level three times that of pure MoSi{sub 2}. Both the room temperature toughness and 1200{degrees}C strength of ZrO/{sub 2}SiC-MoSi{sub 2} composites were higher than ZrO{sub 2}-MoSi{sub 2} composites, indicating beneficial effects of combined reinforcement phases. Low strength levels were observed at 1400{degrees}C due to the presence of the silica glassy phase. Elimination of glassy phases and refinements in microstructural homogeneity are processing routes important to the optimization of the mechanical properties of these types of composites. 18 refs., 7 figs.

Research Organization:
Los Alamos National Lab., NM (United States)
Sponsoring Organization:
DOE; USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
6253688
Report Number(s):
LA-UR-91-3361; CONF-9111115--1; ON: DE92002547
Country of Publication:
United States
Language:
English