Chemical state of vanadium in tin-based yellow pigment

Journal Article · Thu Apr 01 04:00:00 EST 1993 · Journal of the American Ceramic Society; (United States)

DOI:https://doi.org/10.1111/j.1151-2916.1993.tb05322.x· OSTI ID:6251806

Fujiyoshi, Kaichi; Yokoyama, Hisanori ^[1]; Ren, Feng; Ishida, Shingo ^[2]

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1. Gifu Prefectural Ceramic Inst., Tajimi (Japan)
2. Kyoto Inst. of Technology (Japan). Dept. of Chemistry and Materials Technology

Vanadium-tin composite oxides are rather widely used as, for example, yellow pigments for coloring glazes and selective oxidation catalysts for hydrocarbons. Physicochemical states of vanadium in V-doped SnO[sub 2] were studied to clarify the origin of the color of vanadium-tin yellow pigment and its color instability when fired with glaze material. Precision measurements of lattice parameters of V-doped SnO[sub 2] revealed that vanadium was dissolved as V[sup 4+] and its solubility limit was 0.9 wt% as V[sub 2]O[sub 5]. It was found that the color of vanadium-tin yellow was produced by two types of undissolved vanadium on SnO[sub 2] grains. One is poorly crystallized vanadium oxide (v), (V[sub 2]O[sub 5])[prime], having a yellow color, and the other is orange-colored crystalline V[sub 2]O[sub 5]. The structure of (V[sub 2]O[sub 5])[prime] was discussed in connection with its color.

• OSTI ID: 6251806
• Journal Information: Journal of the American Ceramic Society; (United States), Journal Name: Journal of the American Ceramic Society; (United States) Vol. 76:4; ISSN 0002-7820; ISSN JACTAW
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATALYSTS
CHALCOGENIDES
CHEMICAL PROPERTIES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COHERENT SCATTERING
COLOR
DIFFRACTION
DOPED MATERIALS
ELEMENTS
HYDROCARBONS
KINETICS
MATERIALS
METALS
MICROSTRUCTURE
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
ORGANOLEPTIC PROPERTIES
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
REACTION KINETICS
SCATTERING
SOLUBILITY
TIN COMPOUNDS
TIN OXIDES
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
VALENCE
VANADIUM
VANADIUM COMPOUNDS
VANADIUM OXIDES
X-RAY DIFFRACTION