Correlation analysis of the /sup 13/C NMR spectra of some para-substituted benzaldehyde oximes and their anions

Journal Article · Sat Jun 20 00:00:00 EDT 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6250867

Rutkovskii, G V; Zmeikov, V P

For the case of the /sup 13/C NMR spectra of a series of para-substituted benzaldehyde oximes and their anions it was shown that to describe the chemical shifts of all the carbon atoms of the benzene ring and the exocyclic CH group it is necessary to use three-parameter equations with the parameters F and R (which characterize the inductive and resonance effects respectively of the substituents), and Q (which corresponds to the paramagnetic interaction between the substituents and the carbon atoms).

• Research Organization: Institute of Toxicology, Leningrad, USSR
• OSTI ID: 6250867
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:1; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALCOHOLS
ALDEHYDES
AMINES
ANIONS
ATOMIC MODELS
BENZALDEHYDE
CARBON 13
CARBON ISOTOPES
CHARGED PARTICLES
CHEMICAL SHIFT
CORRELATIONS
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
ELECTRON CORRELATION
ELECTRON DENSITY
EVEN-ODD NUCLEI
FOURIER TRANSFORM SPECTROMETERS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
IONIZATION
IONS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MAGNETIC RESONANCE
MATHEMATICAL MODELS
MEASURING INSTRUMENTS
METHANOL
MOLECULES
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIMES
POLYATOMIC MOLECULES
RESONANCE
SPECTRA
SPECTROMETERS
STABLE ISOTOPES