Polybromocyclopentadienes in the diene synthesis reaction. III. Reaction of hexabromo-1,3-cyclopentadiene with dienophiles of the acrylic series

Journal Article · Thu Jan 09 23:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6250488

Mustafaev, A M; Alekperov, N A; Guseinov, M M; Imamaliev, A B; Mekhtiev, S I

The diene synthesis reaction was realized between hexabromo-1,3-cyclopentadiene and dienophiles of the acrylic series, and it was shown that the reaction takes place strictly stereospecifically with the formation of the endo adducts. The kinetics of the reaction were studied, and the activation parameters were determined. In the investigated reaction series the hexabromo-1,3-cyclopentadiene is the diene-acceptor.

• Research Organization: Institute of Organochlorine Synthesis, Sumgait, USSR
• OSTI ID: 6250488
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:8; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETONE
ACRYLIC ACID
ACTIVATION ENERGY
ADDUCTS
ALKENES
BINDING ENERGY
BROMINATED ALIPHATIC HYDROCARBONS
CARBOXYLIC ACIDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
CONFIGURATION INTERACTION
COUPLING
COUPLING CONSTANTS
CYCLOALKENES
CYCLOPENTADIENE
DEUTERIUM COMPOUNDS
DIENES
DIPOLE MOMENTS
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
ENERGY LEVELS
EXCITED STATES
FERMIONS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENS
HYDROCARBONS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INTERMEDIATE COUPLING
IODINE
J-J COUPLING
KETONES
KINETICS
LEPTONS
MAGNETIC DIPOLE MOMENTS
MAGNETIC MOMENTS
MONOCARBOXYLIC ACIDS
MULTIPLETS
NMR SPECTRA
NONMETALS
ORGANIC ACIDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYENES
REACTION KINETICS
SPECTRA
STEREOCHEMISTRY
SYNTHESIS
ULTRAVIOLET SPECTRA
VALENCE
VIBRATIONAL STATES
YIELDS