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Solute transport through large uniform and layered soil columns

Journal Article · · Water Resources Research; (United States)
DOI:https://doi.org/10.1029/92WR02528· OSTI ID:6244850
;  [1];  [2]
  1. New Mexico State Univ., Las Cruces (United States)
  2. Univ. of Arizona, Tucson (United States)
The transport of chemicals in real situations usually takes place in heterogenous soils, unlike laboratory scale experiments, which usually use homogenous, repacked soils in small columns. This experiment was conducted to compare solute transport through uniform and layered soils. The convection-dispersion equation was fit to observed breakthrough curves for tritium, bromide and chloride in uniform and layered 6-m columns. When fitted, the equation provided a reasonable prediction of the overall trend of the observed breakthrough curves in the layered column but only in the upper half of the uniform soil column. This supports the thesis that a uniform soil model can approximate solute transport through layered soils if the length scales of the layers are small relative to the prediction scales and if the transport properties are appropriately chosen. Dispersivities were greater in the uniform column than in the layered column. Dispersion coefficients appeared to be unrelated to depth in both column for the tracers considered. Calibration of the convection-dispersion equation at a shallow depth adequately predicted solute breakthrough at the largest depth in the uniform column, but not in the layered column.
OSTI ID:
6244850
Journal Information:
Water Resources Research; (United States), Journal Name: Water Resources Research; (United States) Vol. 29:4; ISSN WRERAQ; ISSN 0043-1397
Country of Publication:
United States
Language:
English