Frequency dependent polarizabilities for the ground state of H/sub 2/, HD, and D/sub 2/

Journal Article · Wed Jun 15 00:00:00 EDT 1983 · J. Chem. Phys.; (United States)

OSTI ID:6239074

Rychlewski, J

A variation-perturbation method has been employed to calculate the dynamic dipole polarizability for the ground state of the hydrogen molecule. The explicit correlated electronic wave functions were used. The averaged values of ..cap alpha..(..omega..) and ..gamma..(..omega..) for several vibration-rotation states of HD and D/sub 2/ are presented. Similar values for H/sub 2/ have also been calculated and were used to test the efficiency of the method and the validity of the assumption applied in the present calculation. The agreement of the present theoretical results with the existing experimental data is found to be satisfactory.

• Research Organization: Department of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland
• OSTI ID: 6239074
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 78:12; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
DEUTERIUM
ELECTRICAL PROPERTIES
ELEMENTS
ENERGY LEVELS
FREQUENCY DEPENDENCE
GROUND STATES
HALOGEN COMPOUNDS
HYDRIODIC ACID
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INORGANIC ACIDS
IODINE COMPOUNDS
ISOTOPES
LIGHT NUCLEI
NONMETALS
NUCLEI
ODD-ODD NUCLEI
PHYSICAL PROPERTIES
POLARIZABILITY
STABLE ISOTOPES