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U.S. Department of Energy
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Microsegregation observed in Fe-35. 5Ni-7. 5Cr irradiated in EBR-II

Conference ·
OSTI ID:6231945
In another recent study of the compositional dependence of swelling in annealed Fe-Ni-Cr alloys, it was found that some annealed alloys densified during irradiation. No precipitate phases were observed to form however. At 593/sup 0/C one alloy, Fe-35.5Ni-7.5Cr, which was particularly resistant to swelling, increased in density .9% at 7.6 x 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV). Examination by energy dispersive x-ray analysis revealed that substantial oscillations occur in the nickel content of the alloy, varying from 25 to 53% about the nominal level of 35.5%. These oscillations exhibit a period of approx. 200 nm. Regions enriched in nickel are depleted in chromium and iron, and the reverse is true in regions of low nickel content. This spinodal-like process produces a net densification and also appears to eventually destroy the swelling resistance of the alloy. Once voids form in the nickel-poor chromium-rich regions, further segregation of nickel to void surfaces is expected to accelerate the loss of swelling resistance.
Research Organization:
Hanford Engineering Development Lab., Richland, WA (USA)
DOE Contract Number:
AC06-76FF02170
OSTI ID:
6231945
Report Number(s):
HEDL-SA-3027-FP; CONF-840604-24; ON: DE85001657
Country of Publication:
United States
Language:
English