Oxygen ordering and the orthorhombic-to-tetragonal phase transition in YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/
In situ neutron powder diffraction measurements show that the orthorhombic-to-tetragonal phase transition in YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/ which occurs near 700 /sup 0/C in a pure oxygen atmosphere, is an order-disorder transition in which the disordering of oxygen atoms into a normally vacant site destroys the one-dimensional Cu-O chains present in the room-temperature orthorhombic structure. For both structures, the oxygen stoichiometry decreases monotonically with increasing temperature. The transition temperature depends on the oxygen partial pressure and occurs when the stoichiometry is near YBa/sub 2/Cu/sub 3/O/sub 6.5/. The tetragonal structure has a partially occupied, nearly octahedral Cu-O arrangement, in contrast to the orthorhombic structure which has one-dimensional Cu-O chains. The observed depression of the superconducting transition temperature in tetragonal YBa/sub 2/Cu/sub 3/O/sub 7-//sub x/, which has been quenched from high temperature, could result either from the disordering of oxygen atoms which destroys the one-dimensional chains or from the absence of Cu/sup 3+/ ions.
- Research Organization:
- Argonne National Laboratory, Argonne, Illinois 60439
- OSTI ID:
- 6231376
- Journal Information:
- Phys. Rev. B: Condens. Matter; (United States), Vol. 36:7
- Country of Publication:
- United States
- Language:
- English
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75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
BARIUM OXIDES
CRYSTAL-PHASE TRANSFORMATIONS
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YTTRIUM OXIDES
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NEUTRON DIFFRACTION
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SUPERCONDUCTIVITY
ALKALINE EARTH METAL COMPOUNDS
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CHALCOGENIDES
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