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Evaluation of a surface application of limestone for controlling acid mine discharges from abandoned strip mines, Sewellsville, Ohio

Thesis/Dissertation ·
OSTI ID:6231123

A 150 acre drainage basin in an unreclaimed coal strip mine in east-central Ohio was studied and extensively monitored to determine the effect of a surface application of limestone on the ground water quality. Prior to the limestone treatment the ground and surface water of the basin was acidic due to pyrite oxidation in the spoil. In order to assess the effect of limestone application the basin was divided into seven sub-basins, five of which were treated. Various halide salts were also applied in order to ascertain the rate of ground water movement through the spoil. Twenty-six seeps draining the seven basins were monitored on a weekly basis for temperature, pH, acidity, alkalinity, conductivity and the tracers and once a month for sulfate. A recording rain gage was set up in the area and a weekly composite of precipitation was analyzed. The seeps from the sub-basins with low acid concentrations became alkaline due to neutralization but after a long dry period, they returned to their acid condition. The moderately and highly acidic seeps showed a decline in the acid concentrations which could be attributed to a combination of neutralization and a decrease in the rate of pyrite oxidation. The results of this field study and simultaneous laboratory experiments showed that the maximum amount of alkalinity that can be generated by a surface application of limestone is not sufficient to reduce the ground water acidity generated by pyrite oxidation. Additionally, the amount of limestone applied was not sufficient to significantly decrease the rate of pyrite oxidation nor provide neutralization and thereby produce neutral or alkaline discharges from the abandoned coal strip mine sites.

OSTI ID:
6231123
Country of Publication:
United States
Language:
English