Process for hydrocracking hydrocarbons
A process for hydrotreating (hydroprocessing) hydrocarbons and mixtures of hydrocarbons utilizing a catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.01 to about 2 wt. % platinum or palladium, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 2 wt. % rhodium and about 0.1 to about 3.5 wt. % halogen, wherein the platinum or palladium, cobalt and rhodium ae uniformly dispersed throughout the porous carrier material, wherein substantially all of the platinum or palladium is present in the elemental metallic state, wherein substantially all of the rhodium is present in the elemental metal, and wherein substantially all of the catalytically available cobalt is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states, in which process there is effected a chemical consumption of hydrogen. A preferred modifying component for the disclosed catalytic composite is a Group IVA metallic component. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a platinum component, a cobalt component, a rhodium component, and a halogen component, for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ringopening of cyclic hydrocarbons, hydrogenation, etc.
- Assignee:
- UOP Inc.
- Patent Number(s):
- US 4110198
- OSTI ID:
- 6230024
- Country of Publication:
- United States
- Language:
- English
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Hydrocracking hydrocarbons over tri-metallic catalyst
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Related Subjects
020400* -- Petroleum-- Processing
ALUMINIUM COMPOUNDS
CATALYST SUPPORTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COBALT
CRACKING
DECOMPOSITION
ELEMENTS
HALOGENS
HYDROCARBONS
HYDROCRACKING
MECHANICAL STRUCTURES
METALS
NONMETALS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PLATINUM
PLATINUM METALS
PYROLYSIS
REFRACTORY METALS
RHODIUM
SILICATES
SILICON COMPOUNDS
SUPPORTS
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENTS