Negative ions of polyatomic molecules. [Resonance, anions, electron dissociative attachment, electron capture, potential energy, cross sections, yields, lifetime]
Conference
·
OSTI ID:6229133
General concepts relating to, and recent advances in, the study of negative ions of polyatomic molecules are discussed with emphasis on halocarbons. The outline of the paper is as follows: basic electron attachment processes, modes of electron capture by molecules, short-lived transient negative ions, dissociative electron attachment to ground-state molecules, dissociative electron attachment to hot molecules (effects of temperature on electron attachment), parent negative ions, effect of density, nature and state of the medium on electron attachment, electron attachment to electronically-excited molecules, the binding of attached electrons to molecules (electron affinity), and the basic and the applied significance of negative-ion studies. 133 references.
- Research Organization:
- Oak Ridge National Lab., TN (USA); Tennessee Univ., Knoxville (USA). Dept. of Physics
- DOE Contract Number:
- W-7405-ENG-26
- OSTI ID:
- 6229133
- Report Number(s):
- CONF-790344-1
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ANIONS
BINDING ENERGY
CAPTURE
CHARGED PARTICLES
CHEMICAL REACTION YIELD
COLLISIONS
CROSS SECTIONS
DATA FORMS
DISSOCIATION
DOCUMENT TYPES
ELECTRON ATTACHMENT
ELECTRON CAPTURE
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
ENERGY
ENERGY DEPENDENCE
ENERGY LEVELS
GRAPHS
HALOGENATED ALIPHATIC HYDROCARBONS
IONS
ISOLATED VALUES
LIFETIME
MOLECULE COLLISIONS
MOLECULES
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYATOMIC MOLECULES
POTENTIAL ENERGY
RESONANCE
REVIEWS
TEMPERATURE EFFECTS
TOTAL CROSS SECTIONS
TRANSIENTS
YIELDS
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ANIONS
BINDING ENERGY
CAPTURE
CHARGED PARTICLES
CHEMICAL REACTION YIELD
COLLISIONS
CROSS SECTIONS
DATA FORMS
DISSOCIATION
DOCUMENT TYPES
ELECTRON ATTACHMENT
ELECTRON CAPTURE
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
ENERGY
ENERGY DEPENDENCE
ENERGY LEVELS
GRAPHS
HALOGENATED ALIPHATIC HYDROCARBONS
IONS
ISOLATED VALUES
LIFETIME
MOLECULE COLLISIONS
MOLECULES
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYATOMIC MOLECULES
POTENTIAL ENERGY
RESONANCE
REVIEWS
TEMPERATURE EFFECTS
TOTAL CROSS SECTIONS
TRANSIENTS
YIELDS