Oligomer and mixed-metal compounds: Potential multielectron transfer agents: Progress report, July 1, 1988--February 28, 1989
Technical Report
·
OSTI ID:6226499
We have made progress in synthesizing new ligands systems based on 2,2'-bipyridine. These new ligands have potential for designing square planar transition metal complexes and for providing photochemical stability to transition metal photocatalysts. A copper(II) derivative was synthesized and an x-ray structure was obtained to illustrate the coordination character of this new class of ligands. The following have also been synthesized and examined: multimetallic Ru(II), Re(I), Pt, Pd, and bispyridine complexes. 4 figs. (CBS)
- Research Organization:
- North Carolina Univ., Charlotte (USA). Dept. of Chemistry
- DOE Contract Number:
- FG05-84ER13263
- OSTI ID:
- 6226499
- Report Number(s):
- DOE/ER/13263-5; ON: DE89008002
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AZINES
CATALYSTS
CHEMICAL BONDS
CHEMICAL PREPARATION
CHEMISTRY
COBALT COMPLEXES
COMPLEXES
COPPER COMPLEXES
DOCUMENT TYPES
ELECTRON TRANSFER
ENERGY LEVELS
EXCITED STATES
HETEROCYCLIC COMPOUNDS
LIGANDS
LUMINESCENCE
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PALLADIUM COMPLEXES
PHOTOCHEMISTRY
PLATINUM COMPLEXES
PROGRESS REPORT
PYRIDINES
RHENIUM COMPLEXES
RUTHENIUM COMPLEXES
STABILITY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
AZINES
CATALYSTS
CHEMICAL BONDS
CHEMICAL PREPARATION
CHEMISTRY
COBALT COMPLEXES
COMPLEXES
COPPER COMPLEXES
DOCUMENT TYPES
ELECTRON TRANSFER
ENERGY LEVELS
EXCITED STATES
HETEROCYCLIC COMPOUNDS
LIGANDS
LUMINESCENCE
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PALLADIUM COMPLEXES
PHOTOCHEMISTRY
PLATINUM COMPLEXES
PROGRESS REPORT
PYRIDINES
RHENIUM COMPLEXES
RUTHENIUM COMPLEXES
STABILITY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES