Theoretical investigation of the effect of substituents on the reactivity of free radicals. II. Dimerization of phenylthio radicals
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6224903
The effect of substituents on the electronic structure and reactivity of free phenylthio radicals in dimerization processes was studied by quantum-chemical methods. It was concluded that the introduction of both donating and withdrawing substituents leads to an increase in the stability of the radicals and hinders the formation of the respective disulfides.
- Research Organization:
- Institute of Organic Chemistry, Kiev, USSR
- OSTI ID:
- 6224903
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:9; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
ANGULAR MOMENTUM
ATOMIC MODELS
BINDING ENERGY
CHEMICAL BONDS
CHEMICAL REACTIONS
CONFIGURATION INTERACTION
DIMERIZATION
DISSOCIATION ENERGY
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
HARTREE-FOCK METHOD
HETEROCYCLIC COMPOUNDS
LEPTONS
MATHEMATICAL MODELS
MECHANICS
MOLECULAR ORBITAL METHOD
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PARTICLE PROPERTIES
PERTURBATION THEORY
POLYCYCLIC SULFUR HETEROCYCLES
POLYMERIZATION
QUANTUM MECHANICS
RADICALS
SPIN
STABILITY
VALENCE
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
ANGULAR MOMENTUM
ATOMIC MODELS
BINDING ENERGY
CHEMICAL BONDS
CHEMICAL REACTIONS
CONFIGURATION INTERACTION
DIMERIZATION
DISSOCIATION ENERGY
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
HARTREE-FOCK METHOD
HETEROCYCLIC COMPOUNDS
LEPTONS
MATHEMATICAL MODELS
MECHANICS
MOLECULAR ORBITAL METHOD
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PARTICLE PROPERTIES
PERTURBATION THEORY
POLYCYCLIC SULFUR HETEROCYCLES
POLYMERIZATION
QUANTUM MECHANICS
RADICALS
SPIN
STABILITY
VALENCE