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Convenient method for the production of compounds of the brexane, brendane, and noradamantane series

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6224867
; ; ; ; ; ;

Preparative methods are proposed for the production of 5-brexanone and the acetates of 2-brendanol and 2-noradamantanol from cis-bicyclo(4.3.0(nona-3,7-diene. Dehydration of 5-brexanol and 2-brendanol gave 4-brexene and deltacyclane respectively. The /sup 13/C NMR spectra of the compounds of the noradamantane, brexane, brendane, and deltacyclane series were studied.

Research Organization:
M.V. Lomonosov Moscow State Univ., USSR
OSTI ID:
6224867
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:9; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACID HYDROLYSIS
ALCOHOLS
ALKANES
ALKENES
BARYONS
CARBON 13
CARBON ISOTOPES
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
CYCLOALKANES
CYCLOALKENES
DECOMPOSITION
DEUTERIUM COMPOUNDS
DIENES
ELECTRONIC STRUCTURE
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
FORMIC ACID
HADRONS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIDES
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROGEN TRANSFER
HYDROLYSIS
HYDROXY COMPOUNDS
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPE EFFECTS
ISOTOPES
ISOTOPIC EXCHANGE
J-J COUPLING
LIGHT NUCLEI
LYSIS
MOLECULAR STRUCTURE
MONOCARBOXYLIC ACIDS
NMR SPECTRA
NUCLEI
NUCLEONS
ODD-EVEN NUCLEI
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYENES
PROTONS
SOLVOLYSIS
SPECTRA
STABLE ISOTOPES
SYNTHESIS