Bond energies on the cesium halides determined by collision-induced dissociation

Journal Article · Thu Sep 27 00:00:00 EDT 1984 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j150664a009· OSTI ID:6223532

Parks, E K; Wexler, S

The bond energies of the four cesium halides are determined from the threshold for collision-induced dissociation to ion pairs by rare gas atoms. The bond energies (to neutral atoms) are 5.32 +/- 0.08, 4.58 +/- 0.08, 4.00 +/- 0.08, and 3.47 +/- 0.15 eV for CsF, CsCl, CsBr, and CsI, respectively. Except for CsI the ion thresholds are obtained from the sharply peaked cross section vs. energy curves for CsM/sup +/ + X/sup -/ formation (M = rare gas atom; X/sup -/ = halide ion) and for CsI the ion threshold is obtained from the onset of the channel M + Cs/sup +/ + I/sup -/. Comparison is made with bond energies determined by other techniques as well as that derived from the T-Rittner model potential.

• Research Organization: Argonne National Lab., IL
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 6223532
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 88:20; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
BINDING ENERGY
CESIUM COMPOUNDS
DATA
DISSOCIATION
ENERGY
EXPERIMENTAL DATA
INFORMATION
NUMERICAL DATA