Potential dependent surface relaxation of the Pt(001)/electrolyte interface
Journal Article
·
· Physical Review Letters; (United States)
- Materials Sciences Division, Lawrence Berkeley Laboratory, One Cyclotron Road, Berkeley, California 94720 (United States)
X-ray reflectivity measurements were used to determine the structure of the Pt(001)/solution interface as a function of the applied potential in alkaline and acid electrolytes. Unlike the Pt(001)/vacuum interface, the electrolyte interface was found to be unreconstructed at all potentials. The lattice spacing between the first and second layer was found to be a funciton of potential in the region where approximately a monolayer of H was adsorbed. The expansion was up to 2.5% of a lattice spacing (0.05 A) in alkaline electrolyte, and up to 1% of a lattice spacing in acid electrolytes.
- DOE Contract Number:
- AC03-76SF00098; AC02-76CH00016
- OSTI ID:
- 6222881
- Journal Information:
- Physical Review Letters; (United States), Vol. 71:10; ISSN 0031-9007
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLATINUM
SURFACE PROPERTIES
CRYSTAL STRUCTURE
ELECTRIC POTENTIAL
ELECTROLYTES
EXPANSION
INTERFACES
REFLECTIVITY
RELAXATION
X-RAY SPECTROSCOPY
ELEMENTS
METALS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
PLATINUM METALS
SPECTROSCOPY
TRANSITION ELEMENTS
360102* - Metals & Alloys- Structure & Phase Studies
400400 - Electrochemistry
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLATINUM
SURFACE PROPERTIES
CRYSTAL STRUCTURE
ELECTRIC POTENTIAL
ELECTROLYTES
EXPANSION
INTERFACES
REFLECTIVITY
RELAXATION
X-RAY SPECTROSCOPY
ELEMENTS
METALS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
PLATINUM METALS
SPECTROSCOPY
TRANSITION ELEMENTS
360102* - Metals & Alloys- Structure & Phase Studies
400400 - Electrochemistry