Photochemistry and charge transfer chemistry of the platinum group elements
Technical Report
·
OSTI ID:6218925
The research program focuses on the photochemistry and photophysics of dithiolate complexes of the platinum group elements. The specific systems under investigation are square planar complexes of Pt(2) containing one dithiolate chelate and two other ligands to complete the coordination sphere. Several members of the target series of compounds have been synthesized and found to exhibit luminescence in fluid solution. These initial complexes, shown as 1 and 2, possessed a diimine ligand such as bipyridine (bpy), o-phenanthroline (phen) or an alkyl substituted derivative in addition to the dithiolate chelate. For 1 the dithiolate was maleonitriledi-thiolate (mnt) and for 2 it was ethyl-2-cyano-3, 3-dithiolatoacrylate (ecda). Complexes 1 and 2 were observed to be highly solvatochromic, and the emission spectra of selected members gave evidence of multiple emitting states.
- Research Organization:
- Rochester Univ., NY (USA)
- Sponsoring Organization:
- DOE; USDOE, Washington, DC (USA)
- DOE Contract Number:
- FG02-90ER14125
- OSTI ID:
- 6218925
- Report Number(s):
- DOE/ER/14125-1; ON: DE91009153
- Country of Publication:
- United States
- Language:
- English
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Photochemistry and charge transfer chemistry of the platinum group elements
Technical Report
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OSTI ID:653428
Photochemistry and charge transfer chemistry of the platinum group elements
Technical Report
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Related Subjects
440500* -- Thermal Instrumentation-- (1990-)
47 OTHER INSTRUMENTATION
AROMATICS
AZAARENES
AZINES
BIPYRIDINES
BOND ANGLE
BOND LENGTHS
CATIONS
CHARGED PARTICLES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DIMENSIONS
DITHIOLS
DOCUMENT TYPES
ELECTRON TRANSFER
EMISSION SPECTRA
HETEROCYCLIC COMPOUNDS
HYDROGEN IONS
HYDROGEN IONS 1 PLUS
IONS
LENGTH
LUMINESCENCE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHENANTHROLINE-ORTHO
PHENANTHROLINES
PHOTOCHEMISTRY
PLATINUM COMPLEXES
PROGRESS REPORT
PYRIDINES
REAGENTS
REDOX POTENTIAL
REDUCTION
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
THIOLS
TRANSITION ELEMENT COMPLEXES
47 OTHER INSTRUMENTATION
AROMATICS
AZAARENES
AZINES
BIPYRIDINES
BOND ANGLE
BOND LENGTHS
CATIONS
CHARGED PARTICLES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DIMENSIONS
DITHIOLS
DOCUMENT TYPES
ELECTRON TRANSFER
EMISSION SPECTRA
HETEROCYCLIC COMPOUNDS
HYDROGEN IONS
HYDROGEN IONS 1 PLUS
IONS
LENGTH
LUMINESCENCE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHENANTHROLINE-ORTHO
PHENANTHROLINES
PHOTOCHEMISTRY
PLATINUM COMPLEXES
PROGRESS REPORT
PYRIDINES
REAGENTS
REDOX POTENTIAL
REDUCTION
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
THIOLS
TRANSITION ELEMENT COMPLEXES