Oxidation resistant inorganic-porphyrin analog polyoxometalates. 3. The synthesis and X-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog' KLi[sub 15][O[l brace]Ru[sup IV]Cl([alpha][sub 2]-P[sub 2]W[sub 17]O[sub 61])[r brace][sub 2]][center dot]2KCl[center dot]60H[sub 2]O
Journal Article
·
· Inorganic Chemistry; (United States)
- Lewis and Clark College, Portland, OR (United States)
- Univ. of Oregon, Eugene (United States)
The synthesis and unequivocal characterization by X-ray crystallography of a Ru-containing polyoxoanion bimetallic inorganic-porphyrin analog is reported, [O[l brace]Ru[sup IV]Cl([alpha][sub 2]-P[sub 2]W[sub 17]O[sub 61])[r brace][sub 2]][sup 16[minus]]. The structural results reveal a new polyoxoanion structural type, a Ru-O-Ru oxo-bridged-dimer anion that is structurally analogous to bimetallic metalloporphyrins containing a [mu]-oxo M-O-M bridge. Such new types of polyanions are of current interest as oxidation-resistant oxidation catalysts and for their possible multielectron redox reactivity. 28 refs., 2 figs., 2 tabs.
- DOE Contract Number:
- FG06-89ER13998
- OSTI ID:
- 6208878
- Journal Information:
- Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 32:7; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CATALYSTS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL STRUCTURE
CRYSTALLOGRAPHY
DIFFRACTION
HALIDES
HALOGEN COMPOUNDS
MOLECULAR STRUCTURE
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PNICTIDES
REACTIVITY
REFRACTORY METAL COMPOUNDS
RUTHENIUM CHLORIDES
RUTHENIUM COMPOUNDS
RUTHENIUM OXIDES
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN OXIDES
TUNGSTEN PHOSPHIDES
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
CATALYSTS
CHALCOGENIDES
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL STRUCTURE
CRYSTALLOGRAPHY
DIFFRACTION
HALIDES
HALOGEN COMPOUNDS
MOLECULAR STRUCTURE
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PNICTIDES
REACTIVITY
REFRACTORY METAL COMPOUNDS
RUTHENIUM CHLORIDES
RUTHENIUM COMPOUNDS
RUTHENIUM OXIDES
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN OXIDES
TUNGSTEN PHOSPHIDES
X-RAY DIFFRACTION