Products of the neutralization of hydrazine fuels with hypochlorite
Conference
·
OSTI ID:6208568
Neutralization of hydrazine fuels with hypochlorite is a recommended procedure for treatment of fuel spills. Earlier publications have reported some of the major reaction products and have suggested that incomplete reaction and reaction with impurities may lead to formation of environmentally and toxicologically significant substances. The results presented in this paper were obtained as part of a program to assess the environmental implications of using the hypochlorite method for treatment and disposal of hydrazine fuel spills. The fuel sample impurities analyzed, the analytical protocols used, and the chemical compounds produced by neutralization of hydrazine fuels with hypochlorite are discussed. The fuels examined were hydrazine, monomethylhydrazine, unsymmetrical dimethylhydrazine, and Aerozine-50. The neutralization products were determined under experimental conditions comparable to those expected for actual spills. Major products, as well as environmentally significant minor products, were identified using gas-chromatography/mass-spectrometry and gas-chromatography/Fourier-transform-infrared-spectroscopy.
- Research Organization:
- Argonne National Lab., IL (USA)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6208568
- Report Number(s):
- CONF-8511110-4; ON: DE86004049
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
500200 -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
520200* -- Environment
Aquatic-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL PROPERTIES
CHEMICAL SPILLS
CHLORINE COMPOUNDS
CONTROL
DIRECT ENERGY CONVERTERS
ELECTROCHEMICAL CELLS
ENVIRONMENTAL TRANSPORT
FUEL CELLS
GASEOUS WASTES
HALOGEN COMPOUNDS
HYDRAZINE
HYDRAZINE FUEL CELLS
HYDROGEN COMPOUNDS
LIQUID WASTES
MASS TRANSFER
NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PH VALUE
POLLUTION CONTROL
POLLUTION SOURCES
TOXICITY
WASTE WATER
WASTES
WATER
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
520200* -- Environment
Aquatic-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL PROPERTIES
CHEMICAL SPILLS
CHLORINE COMPOUNDS
CONTROL
DIRECT ENERGY CONVERTERS
ELECTROCHEMICAL CELLS
ENVIRONMENTAL TRANSPORT
FUEL CELLS
GASEOUS WASTES
HALOGEN COMPOUNDS
HYDRAZINE
HYDRAZINE FUEL CELLS
HYDROGEN COMPOUNDS
LIQUID WASTES
MASS TRANSFER
NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PH VALUE
POLLUTION CONTROL
POLLUTION SOURCES
TOXICITY
WASTE WATER
WASTES
WATER