Radio-frequency optical double-resonance spectrum of SrF: the X/sup 2/. sigma. /sup +/ state

Journal Article · Thu Jan 01 04:00:00 EST 1981 · J. Mol. Spectrosc.; (United States)

DOI:https://doi.org/10.1016/0022-2852(81)90422-7· OSTI ID:6199762

Childs, W J; Goodman, L S; Renhorn, I

The isotropic and anisotropic hyperfine constants of the ground X/sup 2/..sigma../sup +/ state of /sup 88/SrF and /sup 86/SrF are reported. Vibrational and rotational dependences are studied in a Dunham expansion analysis. Furthermore, the vibrational, rotational, and isotopic dependence of the spin-rotation constant is determined. The following values are obtained for X/sup 2/..sigma../sup +/, ..nu.. = 0, in /sup 88/SrF: ..gamma../sub 0/ = 74.79485 MHz, ..gamma../sub 1/ = 5.752 x 10/sup -5/ MHz, ..gamma../sub 2/ = -6.3 x 10/sup -10/ MHz, b/sub 0/ = 97.0834 MHz, b/sub 1/ = -3.300 x 10/sup -4/ MHz, c/sub 0/ = 30.268 MHz, C/sub I/ = 0.00230 MHz, where ..gamma.. is the spin-rotation parameter, b and c are the Frosch and Foley hyperfine parameters, and C/sub I/ is a nuclear spin-rotation correction. 4 figures, 4 tables.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 6199762
• Journal Information: J. Mol. Spectrosc.; (United States), Journal Name: J. Mol. Spectrosc.; (United States) Vol. 87; ISSN JMOSA
• Country of Publication: United States
• Language: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALINE EARTH ISOTOPES
ALKALINE EARTH METAL COMPOUNDS
ANISOTROPY
EMISSION SPECTROSCOPY
ENERGY LEVELS
EVEN-EVEN NUCLEI
EXCITED STATES
FLUORESCENCE SPECTROSCOPY
FLUORIDES
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GROUND STATES
HALIDES
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HYPERFINE STRUCTURE
INTERMEDIATE MASS NUCLEI
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LASER SPECTROSCOPY
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SPECTROSCOPY
SPIN ORIENTATION
STABLE ISOTOPES
STRONTIUM 86
STRONTIUM 88
STRONTIUM COMPOUNDS
STRONTIUM FLUORIDES
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VIBRATIONAL STATES