Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Compounds of the methane series. XX. Determination of the stereochemical structure of the stereomeric 2- and 4-methyl-1-(1-hydroxy-1-methylethyl)cyclohexanes by the /sup 13/C and /sup 1/H NMR methods

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6191616
;

The stereochemical structure of the stereomeric 2- and 4-methyl-1-(1-hydroxy-1-methylethyl)cyclohexanes was established by /sup 13/C and /sup 1/H NMR spectroscopy. It was shown that the chair conformation of the ring in trans-2-methyl-1-(1-hydroxy-1-methylethyl)cyclohexane is distorted. The investigated compounds are mostly conformationally uniform. The effect of the stereochemical structure on the reactivity of the compounds was examined.

Research Organization:
V.I. Ul'yanov-Lenin Kazan' State Univ., USSR
OSTI ID:
6191616
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:2; ISSN JOCYA
Country of Publication:
United States
Language:
English

Similar Records

Stereochemistry of seven-membered heterocycles. communication 16. dipole moments, IR, /sup 1/H, and /sup 13/C nmr spectra, and conformations of 4-methyl-, 4-phenyl-, and isomeric 4,7-dimethyl-2,2-pentamethylene-1,3-dioxa-5,6-benzocycloheptenes
Journal Article · Mon Dec 09 23:00:00 EST 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) · OSTI ID:5035778
Solid-state NMR study of cyclohexane reorientation and inversion in (N-methyl-1,3-diaminopropane)cadmium(II) tetracyanonickelate(II)-cyclohexane (2/1) clathrate
Journal Article · Thu Oct 18 00:00:00 EDT 1990 · Journal of Physical Chemistry; (USA) · OSTI ID:6259106
Application of /sup 1/H and /sup 13/C NMR spectroscopy in structural investigations of Vinca indole alkaloids
Journal Article · Tue Jul 01 00:00:00 EDT 1986 · Chem. Nat. Compd. (Engl. Transl.); (United States) · OSTI ID:6812141

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKALI METAL COMPOUNDS
ALKANES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CARBON 13
CARBON ISOTOPES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COMPLEXES
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
CYCLOALKANES
CYCLOHEXANE
DEHYDRATION
DEUTERIUM COMPOUNDS
ELECTRONIC STRUCTURE
EUROPIUM COMPLEXES
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MOLECULAR STRUCTURE
MULTIPLETS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
POTASSIUM SULFATES
RARE EARTH COMPLEXES
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SULFATES
SULFUR COMPOUNDS