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Reaction of 3-aryl-2-benzoyloxiranes with alkyl thiocyanates

Journal Article · · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)
OSTI ID:6181581
; ;
3-Aryl-2-benzoyloxiranes and alkyl thiocyanates in the presence of an equivalent amount of anhydrous AlCl/sub 3/ form erythro-N-(2-benzoyl-1-aryl-2-chloroethyl)-S-alkyl thiocarbamates and ..cap alpha..-diketones. p-Tolyl- and p-anisyl-2-benzoyl-oxiranes do not react with alkyl thiocyanates, but isomerize to the respective ..cap alpha..-diketones, and form the threo-chlorohydrins in low yield.
Research Organization:
V.I. Lenin Belorussian State Univ., Minsk, USSR
OSTI ID:
6181581
Journal Information:
Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 21:12; ISSN CHCCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALUMINIUM CHLORIDES
ALUMINIUM COMPLEXES
ALUMINIUM COMPOUNDS
ANTITHYROID DRUGS
BINDING ENERGY
BORON COMPOUNDS
BORON FLUORIDES
CARBAMATES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATION
CHLORINE COMPOUNDS
CHLOROFORM
COMPLEXES
COMPLEXOMETRY
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DRUGS
ELECTRONIC STRUCTURE
ENERGY
EPOXIDES
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HETEROCYCLIC COMPOUNDS
HORMONE ANTAGONISTS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
KETONES
KINETICS
MASS SPECTRA
MECHANICS
MOLECULAR ORBITAL METHOD
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
QUANTUM MECHANICS
REACTION KINETICS
SPECTRA
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
THIOCYANATES