Nitro- and amino-substituted 10,10-dimethyl-10-sila-2-azaanthrones

Journal Article · Thu May 01 00:00:00 EDT 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

OSTI ID:6181541

Prostakov, N S; Nazrul, I; Varlamov, A V

Under conditions of the Mencke reaction, 10,10-dimethyl-9,10-dihydro-10-sila-2-azaanthracene is nitrated on the benzene fragment of the molecule, but the corresponding ketone is nitrated on the pyridine fragment. Dihydrosilaazaanthrone is nitrated by nitrating mixture in positions 5, 7, and 8 of the benzene fragment of the molecule. The nitro-substituted dihydrosilazaanthrones have been reduced to the corresponding amino derivatives.

• Research Organization: P. Lumumba People's Friendship Univ., Moscow, USSR
• OSTI ID: 6181541
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Vol. 21:11; Other Information: Translated from Khim. Geterotsikl. Soedin.; 21: No.11, 1528-1531(Nov 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
AMINES
SYNTHESIS
CONDENSED AROMATICS
AMINATION
NITRATION
HETEROCYCLIC COMPOUNDS
KETONES
NICKEL
CATALYTIC EFFECTS
NITRO COMPOUNDS
SILICON COMPLEXES
ALUMINIUM NITRATES
ANTHRACENE
CHEMICAL REACTION YIELD
COPPER NITRATES
ELECTRON DENSITY
ELECTRONIC STRUCTURE
EXCITATION
IRON NITRATES
NMR SPECTRA
QUANTUM MECHANICS
SILANES
ULTRAVIOLET SPECTRA
ALUMINIUM COMPOUNDS
AROMATICS
CHEMICAL REACTIONS
COMPLEXES
COPPER COMPOUNDS
ELEMENTS
ENERGY-LEVEL TRANSITIONS
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
IRON COMPOUNDS
MECHANICS
METALS
NITRATES
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SILICON COMPOUNDS
OXYGEN COMPOUNDS
SILICON COMPOUNDS
SPECTRA
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
YIELDS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory