Frontier orbital symmetry control of intermolecular electron transfer

Technical Report · Wed Oct 31 23:00:00 EST 1990

DOI:https://doi.org/10.2172/6178953· OSTI ID:6178953

Stevens, B

Research continued on the study of intermolecular electron transfer. This report discusses the following topics: fluorescence quenching by electron transfer and the modification of quenching dynamics by solvent properties and net free energy change; transient absorption measurements following selective excitation of 1:1 EDA complex isomers; selective quenching of dual fluorescence from linked EDA systems; electron-transfer sensitized cycloreversion of rubrene endoperoxide; and vibronic modification of adiabatic requirements for intermolecular electron transfer. (CBS)

• Research Organization: University of South Florida, Tampa, FL (USA). Dept. of Chemistry
• Sponsoring Organization: DOE/ER
• DOE Contract Number: FG05-88ER13975
• OSTI ID: 6178953
• Report Number(s): DOE/ER/13975-2; ON: DE91005699
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
CARBON TETRACHLORIDE
CHLORINATED ALIPHATIC HYDROCARBONS
CONDENSED AROMATICS
DOCUMENT TYPES
ELECTRON TRANSFER
FLUORESCENCE
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
LUMINESCENCE
NAPHTHALENE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SOLVENTS
PROGRESS REPORT
QUENCHING
SOLVENTS
TEMPERATURE DEPENDENCE