Catalytic hydrotreatment studies with model compounds. Quarterly report, July 1-September 30, 1984

Technical Report · Sun Jan 01 04:00:00 EST 1984

OSTI ID:6170166

Satterfield, C N; Smith, C M

From studies at 375/sup 0/C, and 6.9 MPa on a presulfided NiMo/Al/sub 2/O/sub 3/ catalyst it is shown that water vapor moderately increases the hydrodenitrogenation rate of quinoline, in either the presence or absence of H/sub 2/S. It does not significantly affect hydrogenation reactions in the reaction network but increases hydrogenolysis. Several changes in product distribution upon addition of water suggest that it increases the catalyst acidity. 11 references, 18 figures, 2 tables.

• Research Organization: Massachusetts Inst. of Tech., Cambridge (USA). Dept. of Chemical Engineering
• DOE Contract Number: FG22-83PC60798
• OSTI ID: 6170166
• Report Number(s): DOE/PC/60798-4; ON: DE85001847
• Country of Publication: United States
• Language: English

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ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AROMATICS
AZAARENES
AZINES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
DENITRIFICATION
ELEMENTS
EXPERIMENTAL DATA
FLUIDS
GASES
HETEROCYCLIC COMPOUNDS
HIGH TEMPERATURE
HYDROGENATION
INFORMATION
MEDIUM PRESSURE
METALS
MOLYBDENUM
NICKEL
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PYRIDINES
QUINOLINES
STRUCTURAL MODELS
SULFIDATION
TEMPERATURE DEPENDENCE
TRANSITION ELEMENTS
VAPORS
WATER VAPOR