Satellite structures in the ESCA spectra of (diphthalocyaninato)lanthanides(III) and -actinides(IV)
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Lanthanides studied include lanthanum, cerium, praseodymium, neodymium, and gadolinium; actinides are thorium and uranium. The results of their x-ray photoelectron spectroscopy and the satellites accompanying lanthanide 3d/sub 5/2/ and actinide 4d/sub 5/2/ signals are reported. Interpretation is based on the hypothesis that half-occupied f orbitals play an important role in the striking change of the satellite intensity throughout the f transition metal series. The binding energies of the main 3d/sub 5/2/ and 4d/sub 5/2/ peaks and their satellites are reported along with the intensity ratio of the satellie to the main line. 1 figure, 1 table.
- Research Organization:
- Texas A and M Univ., College Station
- OSTI ID:
- 6168700
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 101:2; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPLEXES
BINDING ENERGY
CERIUM COMPLEXES
COMPARATIVE EVALUATIONS
COMPLEXES
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ENERGY
GADOLINIUM COMPLEXES
LANTHANUM COMPLEXES
NEODYMIUM COMPLEXES
PHOTOELECTRON SPECTROSCOPY
PRASEODYMIUM COMPLEXES
RARE EARTH COMPLEXES
SPECTROSCOPY
STRUCTURAL CHEMICAL ANALYSIS
THORIUM COMPLEXES
URANIUM COMPLEXES
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPLEXES
BINDING ENERGY
CERIUM COMPLEXES
COMPARATIVE EVALUATIONS
COMPLEXES
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ENERGY
GADOLINIUM COMPLEXES
LANTHANUM COMPLEXES
NEODYMIUM COMPLEXES
PHOTOELECTRON SPECTROSCOPY
PRASEODYMIUM COMPLEXES
RARE EARTH COMPLEXES
SPECTROSCOPY
STRUCTURAL CHEMICAL ANALYSIS
THORIUM COMPLEXES
URANIUM COMPLEXES